‹ Class 9 · Ch 9
Atomic Foundations of Matter · Principle 15 of 30

No prefix before hydrogen

Hydrogen first, and common names.

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NCERT: 9.4.1 Bonding by sharing of electrons—Covalent Bond

Think

Two hydrogens, but no di-?

H₂S has two hydrogen atoms and one sulfur atom. By the prefix rule you might expect dihydrogen sulfide.

What do you think the compound H₂S is called?

What this lesson covers

The idea

No prefix is added before hydrogen when it is the first element in a formula, whatever the number of its atoms, and a few binary compounds are known only by their common names.

Two hydrogens, but no di-?

H₂S has two hydrogen atoms and one sulfur atom. By the prefix rule you might expect dihydrogen sulfide.

What do you think the compound H₂S is called?

  • Hydrogen sulfide
  • Dihydrogen sulfide
  • Hydrogen monosulfide

Match formula and name

Match each formula with the name used for it.

Two exceptions

When hydrogen is the first element in a formula, no prefix is added before it. A few binary compounds are known only by their common names.

No prefix is added before hydrogen when it is the first element in a formula, whatever the number of its atoms. A few binary compounds are known only by their common names.

  • Formula | Name used | Name by the prefix system
  • H₂S | hydrogen sulfide | not dihydrogen sulfide
  • H₂O | water | hydrogen monoxide
  • NH₃ | ammonia | nitrogen trihydride

Notes

No prefix before hydrogen when it is first in the formula. A few binary compounds, like H₂O (water) and NH₃ (ammonia), keep their common names.

Check yourself

What is H₂S named?

Why is there no prefix before hydrogen in the name hydrogen sulfide?

What is NH₃ commonly known as?

What would the prefix system call H₂O?

  • Dihydrogen sulfide. No prefix is added before hydrogen when it is the first element, whatever the number of its atoms.
  • Hydrogen sulfide — correct. Yes!
  • Hydrogen disulfide. There is one sulfur atom, so there is no di- on sulfide.
  • Hydrogen is a gas. The rule depends on hydrogen being the first element in the formula, not on its state.
  • The formula has only one atom of hydrogen. H₂S has two hydrogen atoms. The rule applies whatever the number of hydrogen atoms.
  • Hydrogen is the first element in the formula — correct. Yes!
  • Ammonia — correct. Yes!
  • Hydrogen nitride. NH₃ is known by its common name, ammonia. Its prefix name is nitrogen trihydride.
  • Water. Water is the common name of H₂O, not of NH₃.
  • Dihydrogen monoxide. No prefix is added before hydrogen when it is the first element.
  • Hydrogen monoxide — correct. Yes!
  • Hydrogen dioxide. There is one oxygen atom, which is mono-, not di-.
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