Ammonium Salt Test

Detect ammonium ions with heat and NaOH.

Setting up the bench…

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Selina ICSE: Analytical Chemistry

What this lesson covers

Why it matters

Heat a mixture of ammonium chloride and sodium hydroxide, and a pungent gas escapes that turns red litmus blue.

The idea in plain words

Verify the balanced equation: NH₄Cl + NaOH → NaCl + H₂O + NH₃.

Predict first

What gas is released when ammonium salts are heated with a strong base like NaOH?

Ammonium ions react with hydroxide ions to form water and ammonia gas.

  • Hydrogen chloride (HCl)
  • Ammonia (NH₃) — correct
  • Nitrogen (N₂)
  • Oxygen (O₂)

What you do

Heat the mixture. Observe the gas evolution and test it with moist red litmus paper.

Check yourself

How do you confirm the gas is ammonia?

Ammonia is alkaline; it turns moist red litmus paper blue.

Why is heat required for this reaction?

Heating provides the energy needed to drive the double decomposition reaction forward.

What is the nature of the gas produced?

Ammonia dissolves in water to form ammonium hydroxide, which is alkaline.

  • It relights a glowing splint
  • It turns moist red litmus blue — correct
  • It turns moist blue litmus red
  • It produces a pop sound
  • To melt the sodium hydroxide
  • To provide activation energy for the decomposition — correct
  • To evaporate the water produced
  • To break the ionic bonds in NaCl
  • Acidic
  • Neutral
  • Alkaline — correct
  • Oxidizing
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