Ammonia Redox Reactions

React ammonia with copper oxide and chlorine

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Selina ICSE: Study of Compounds B. Ammonia

What this lesson covers

Why it matters

Ammonia is usually a base, but here it acts as a reducing agent — stripping oxygen from copper oxide, or reducing chlorine to HCl. Watch how nitrogen gas emerges from both reactions.

The idea in plain words

Analyze the redox change: Copper goes from +2 to 0. Nitrogen goes from -3 to 0. Who is the reducing agent?

Predict first

When ammonia reacts with heated copper oxide, what happens to the ammonia?

Ammonia acts as a reducing agent. It removes oxygen from CuO, becoming oxidized itself to N₂.

  • It gains oxygen to form nitric acid
  • It loses hydrogen and is oxidized to nitrogen gas — correct
  • It acts as a base and forms ammonium oxide

What you do

Run both reactions. Observe the formation of reddish-brown copper in the first and the reduction of chlorine to HCl in the second. Note the common product.

Check yourself

In the reaction 3CuO + 2NH₃ → 3Cu + 3H₂O + N₂, what is the visible change in the solid?

CuO (black) is reduced to Cu (reddish-brown).

What is the common gaseous product in both ammonia reactions?

Both equations produce N₂.

In 2NH₃ + 3Cl₂ → N₂ + 6HCl, ammonia acts as a:

Ammonia is oxidized to N₂, so it reduces Cl₂ to HCl.

  • Black powder turns to reddish-brown metal — correct
  • Black powder turns to white ash
  • The solid dissolves into a blue solution
  • Hydrogen gas
  • Nitrogen gas — correct
  • Ammonia gas
  • Chlorine gas
  • Reducing agent — correct
  • Oxidizing agent
  • Catalyst
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