CFCs Destroy Ozone

Chlorine radicals break down the ozone layer

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Selina ICSE: Atmospheric Pollution

What this lesson covers

Why it matters

A single chlorine atom acts like a tiny wrecking ball, smashing through the ozone shield one molecule at a time.

The idea in plain words

Verify the stoichiometry: one Cl and one O₃ yield one ClO and one O₂.

Predict first

What happens when a chlorine atom collides with an ozone molecule?

Chlorine is highly reactive; it rips an oxygen atom from ozone, creating chlorine monoxide (ClO) and leaving behind ordinary oxygen (O₂).

  • They bond permanently to form a stable ClO₃ compound.
  • Chlorine steals an oxygen atom, forming ClO and releasing O₂. — correct
  • The ozone molecule splits into three oxygen atoms, ignoring the chlorine.
  • Chlorine is too heavy to react with light ozone gas.

What you do

Arrange the steps of the chlorine wrecking-ball cycle. Notice the chlorine atom comes out untouched at the end — ready to destroy again. That's why one Cl can wreck ~100,000 ozone molecules.

Check yourself

Why is a single chlorine atom so dangerous to the ozone layer?

The Cl atom is regenerated in subsequent steps, allowing it to destroy ~100,000 ozone molecules.

Identify the correct chemical equation for this step.

The reaction data confirms: Cl + O₃ → ClO + O₂.

What type of reaction is Cl + O₃ → ClO + O₂?

Oxygen is transferred from ozone to chlorine (Cl gains O to become ClO), so it is a redox change.

  • It destroys only one ozone molecule before becoming inert.
  • It acts as a catalyst, destroying ~100,000 ozone molecules. — correct
  • It blocks sunlight, causing ozone to freeze.
  • Cl + O₃ → ClO + O₂ — correct
  • Cl₂ + O₃ → 2ClO + O₂
  • Cl + O₂ → ClO + O
  • ClO + O₃ → Cl + 2O₂
  • Redox — correct
  • Neutralization
  • Precipitation
  • Combustion
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